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Polyphosphoric Acid(PPA)

Polyphosphoric Acid(PPA)
CAS No.: 8017-16-1
Molecular Formula:H3O4P
Molecular Weight:337.93
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Product Introduction

Polyphosphoric acid (PPA) is a mixture of linear polymers formed through the dehydration and condensation of phosphoric acid molecules. At room temperature, it is a colorless, viscous liquid characterized by strong dehydrating properties, Brønsted acidity, and corrosiveness; it is widely used as a catalyst for cyclization and acylation reactions in organic synthesis.


CHEMICAL PROPERTIES

Chinese NamePolyphosphoric Acid
English NamePolyphosphoric acid; Tetraphosphoric acid
AliasTetraphosphoric acid
Chemical FormulaHn+2PnO3n+1
Molecular Weight18+79.98n
CAS Registry No.8017-16-1
EINECS No.232-417-0
Melting Point48 ~ 50 °C
Boiling Point856 °C
AppearanceColorless viscous liquid
Safety PhrasesS25; S36/37/38; S45
Hazard SymbolC (Corrosive)
Risk PhraseR34
UN Dangerous Goods No.3264


PRODUCT USAGE

Organic Synthesis: Serves as a key cyclizing agent, acylating agent, and dehydrating agent in processes such as Fischer-Indole synthesis, the Beckmann rearrangement, and condensation reactions; functions as both a solvent and a catalyst.

Industrial Auxiliaries: Used as a catalyst for petroleum alkylation, in metal surface treatment (phosphating), as a raw material for flame retardants, as an analytical reagent, and as a substitute for orthophosphoric acid.

Derivative Applications: Its salts (e.g., sodium polyphosphate) are used as food water-retention agents and chelating agents for water treatment; however, polyphosphoric acid itself is not used directly in food.

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